In Situ Katalitik Basa pada Proses Pembuatan Biodiesel dari Mikroalga Nannochloropsis sp
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Abstract
Biodiesel merupakan salah satu bahan bakar alternatif yang dapat digunakan sebagai pengganti bahan bakar fosil. Mikroalga Nannochloropsis sp merupakan bahan baku terbarukan yang mampu menghasilkan lipid hingga 68% dan berpotensi untuk dijadikan bahan baku pembuatan biodiesel. Penelitian ini bertujuan untuk mengetahui pengaruh variasi konsentrasi katalis NaOH dan suhu yang digunakan terhadap biodiesel yang dihasilkan dari biomassa Nannochloropsis sp yang digunakan sebagai bahan baku, serta menguji densitas dan viskositas dari crude biodiesel yang dihasilkan. Metode yang digunakan dalam pembuatan biodiesel ini yaitu in situ transesterifikasi menggunakan katalis NaOH 1% dan 2%, pada temperatur 50 dan 60 , dan pada tekanan atmosfer. Hasil penelitian menunjukan bahwa penambahan konsentrasi katalis NaOH 2% meningkatkan yield crude biodiesel menjadi 71,03%, densitas dan viskositas crude biodiesel yang mendekati standar SNI adalah 833,75 kg/m3 dan 1,3579 cSt dengan kondisi operasi pada suhu 50oC dan konsentrasi katalis NaOH 2%.
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References
[2] M. Mahfud, BIODIESEL Perkembangan Bahan Baku & Teknologi. Surabaya, Indonesia: Putra Media Nusantara, 2018.
[3] D. S. Prayanto, M. Salahudin, L. Qadariyah, dan M. Mahfud, “Pembuatan biodiesel dari Minyak Kelapa Dengan katalis NaOH Menggunakan Gelombang Mikro (microwave) Secara Kontinyu,” Jurnal Teknik ITS, vol. 5, no. 1, 2016.
[4] X.-N. Ma, T.-P. Chen, B. Yang, J. Liu, dan F. Chen, “Lipid production from nannochloropsis,” Marine Drugs, vol. 14, no. 4, p. 61, 2016.
[5] A. J. Dassey dan C. S. Theegala, “Harvesting economics and strategies using centrifugation for cost effective separation of microalgae cells for biodiesel applications,” Bioresource Technology, vol. 128, pp. 241–245, 2013.
[6] D. Y. C. Leung, X. Wu, dan M. K. H. Leung, “A review on biodiesel production using catalyzed transesterification,” Applied Energy, vol. 87, no. 4, pp. 1083–1095, 2010.
[7] N. F. Widyaningrum, B. Susilo, dan M. B. Hermanto, “Studi Eksperimental Fotobioreaktor Photovoltaic untuk Produksi Mikroalga (Nannochloropsis oculata),” Bioproses Komoditas Tropis, vol. 1, 2013.
[8] S. Praharyawan, “Peningkatan Produksi Biomassa Sebagai Strategi Jitu dalam Mempercepat Produksi Biodiesel Berbasis Mikroalga di Indonesia,” Bioteknologi & Biosains Indonesia, vol. 8, no. 2021, 2021.
[9] G. Bauer, S. Lima, J. Chenevard, M. Sugnaux, dan F. Fischer, “Biodiesel via in situ wet microalgae biotransformation: Zwitter-type ionic liquid supported extraction and transesterification,” ACS Sustainable Chemistry & Engineering, vol. 5, no. 2, pp. 1931–1937, 2017.
[10] D. Fithriani, D. Ambarwaty, dan Nurhayati, “Identification of bioactive compounds from nannochloropsis sp..,” IOP Conference Series: Earth and Environmental Science, vol. 404, no. 1, p. 012064, 2020.
[11] S. B. Velasquez-Orta, J. G. M. Lee, dan A. Harvey, “Alkaline in situ transesterification of Chlorella vulgaris,” Fuel, vol. 94, pp. 544–550, 2012.
[12] I. Samosir, B. Gusman, dan L. Buchori, “Pengaruh Katalis Asam (H2so4) dan Suhu Reaksi dalam Pembuatan Biodiesel dari Limbah Minyak Ikan,” Teknologi Kimia dan Industri, vol. 1, 2012.
[13] J. K. Efavi, D. Kanbogtah, V. Apalangya, E. Nyankson, E. K. Tiburu, D. Dodoo-Arhin, B. Onwona-Agyeman, dan A. Yaya, “The effect of NaOH catalyst concentration and extraction time on the yield and properties of citrullus vulgaris seed oil as a potential biodiesel feed stock,” South African Journal of Chemical Engineering, vol. 25, pp. 98–102, 2018.
[14] G. Montero dan M. Stoytcheva, Eds., Biodiesel- quality, emissions and by-products. Rijeka, Croatia: InTech, 2011.
[15] Y. H. Tan, M. O. Abdullah, J. Kansedo, N. M. Mubarak, Y. S. Chan, dan C. Nolasco-Hipolito, “Biodiesel production from used cooking oil using green solid catalyst derived from calcined fusion waste chicken and fish bones,” Renewable Energy, vol. 139, pp. 696–706, 2019.